Simultaneous Removal of Pb2+ and Zn2+ Heavy Metals Using Fly Ash Na-X Zeolite and Its Carbon Na-X(C) Composite
Artykuł w czasopiśmie
MNiSW
140
Lista 2021
| Status: | |
| Autorzy: | Panek Rafał, Medykowska Magdalena, Wiśniewska Małgorzata, Szewczuk-Karpisz Katarzyna, Jędruchniewicz Katarzyna, Franus Małgorzata |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2021 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 11 |
| Wolumen/Tom: | 14 |
| Numer artykułu: | 2832 |
| Strony: | 1 - 17 |
| Web of Science® Times Cited: | 32 |
| Scopus® Cytowania: | 35 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Finansowanie: | This work was financed by the National Centre for Research and Development project Lider contract number LIDER/19/0072/L-9/17/NCBR/2018. |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | TAK |
| Licencja: | |
| Sposób udostępnienia: | Witryna wydawcy |
| Wersja tekstu: | Ostateczna wersja opublikowana |
| Czas opublikowania: | W momencie opublikowania |
| Data opublikowania w OA: | 25 maja 2021 |
| Abstrakty: | angielski |
| Pure zeolite (Na-X) and a zeolite–carbon composite (Na-X(C)) were investigated as adsorbents of heavy metals—Pb2+ and Zn2+ from an aqueous solution. These materials were synthesized from fly ash—a waste from conventional hard coal combustion. Both solids were characterized using XRD, SEM-EDS, nitrogen adsorption/desorption, particle size and elemental composition analyses. The adsorption study was performed at pH 5 in the systems containing one or two adsorbates simultaneously. The obtained results showed that the pure zeolite was characterized by a more developed surface area (728 m2/g) than its carbon composite (272 m2/g), and the mean pore diameters were equal to 1.73 and 2.56 nm, respectively. The pure Na-X zeolite showed better adsorption properties towards heavy metals than its Na-X(C) composite, and Zn2+ adsorbed amounts were significantly higher than the Pb2+ ones (the highest experimental adsorption levels were: for Zn2+—656 and 600 mg/g, and for Pb2+—575 and 314 mg/g, on the Na-X and Na-X(C) surfaces, respectively). The zinc ions are exchanged with the cations inside the zeolite materials structure more effectively than lead ions with a considerably larger size. In the mixed systems, the competition between both heavy metals for access to the active sites on the adsorbent surface leads to the noticeable reduction in their adsorbed amounts. Moreover, the hydrochloric acid was a better desorbing agent for both heavy metals, especially Pb2+ one (desorption reached 78%), than sodium base (maximal desorption 25%). |
