Polyassociative Model of A2B6 Semiconductor Melt and p-T-x Phase Equilibria in Zn-Cd-Te System
Artykuł w czasopiśmie
Status: | |
Autorzy: | Moskvin Pavel P., Antonov Maxim, Olchowik Grażyna, Olchowik Jan, Zdyb Agata, Gułkowski Sławomir, Sadowski Wojciech |
Rok wydania: | 2011 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Numer czasopisma: | 1 |
Wolumen/Tom: | 15 |
Strony: | 121 - 130 |
Efekt badań statutowych | NIE |
Materiał konferencyjny: | NIE |
Publikacja OA: | NIE |
Abstrakty: | angielski |
This work presents a numerical analysis of p-T-x phase equilibrium in the Zn-Cd-Te ternary system in the framework of the polyassociative solution model. On the basis of the experimental data on p-T-x phase equilibrium in the ternary system, thermodynamic functions describing the formation of liquid associates were found. It was shown that the results of the mixing of components in the Zn-Cd-Te ternary melt are related to the occurrence of ZnCdTe and ZnCdTe3 associates. Dissociation parameters of these complexes were calculated and subsequently used in order to efficiently describe p-T-x phase equilibrium of the system in a wide temperature range. |