Environmental-Friendly Modifications of Zeolite to Increase Its Sorption and Anion Exchange Properties, Physicochemical Studies of the Modified Materials
Artykuł w czasopiśmie
MNiSW
140
Lista 2021
| Status: | |
| Autorzy: | Cieśla Jolanta, Franus Wojciech, Franus Małgorzata, Kędziora Karolina, Głuszczyk Justyna, Szerement Justyna, Józefaciuk Grzegorz |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2019 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 19 |
| Wolumen/Tom: | 12 |
| Numer artykułu: | 3213 |
| Strony: | 1 - 13 |
| Web of Science® Times Cited: | 18 |
| Scopus® Cytowania: | 20 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | TAK |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | TAK |
| Licencja: | |
| Sposób udostępnienia: | Witryna wydawcy |
| Wersja tekstu: | Ostateczna wersja opublikowana |
| Czas opublikowania: | W momencie opublikowania |
| Data opublikowania w OA: | 30 września 2019 |
| Abstrakty: | angielski |
| Zeolites, naturally possessing a high negative surface charge and large specific surface, are used in agriculture as cationic fertilizers, water holders, heavy metals, and organic pollutants sorbents. Since some nutrients occur in anionic forms, there is a need to modify the zeolite surface to hold anions. In this study, hydrogen (hydrochloric acid), iron (Fe2+ and Fe3+), and aluminum cations as well as the influence of sodium hydroxide modifiers on the specific surface area, water vapor, adsorption energy, fractal dimension, mesopore volumes and radii, electrokinetic (zeta) potential, and isoelectric point were investigated. The use of alkali solution did not affect the zeolite properties significantly, whereas hydrogen, iron, and treatments with aluminum cations resulted in an increase in the specific surface area, mesopore volumes, and radii, and a decrease in the water-binding forces. Aluminum cations were the most effective in recharging the zeolite surface from negative to positive, shifting the isoelectric point toward the highest values. Calcination enlarged the negative surface charge and mesopore radius, and diminished the surface area and mesopore volume. The modified zeolites are promising carriers of anionic nutrients, large surface area sorbents, and suppliers of water for plant roots in soil. |
