Binuclear furanyl-azine metal complexes encapsulated in NaY zeolite as efficiently heterogeneous catalysts for phenol hydroxylation
Artykuł w czasopiśmie
MNiSW
70
Lista 2021
| Status: | |
| Autorzy: | Kuźniarska-Biernacka Iwona, Raposo Manuela M., Batista Rosa M. F., Soares Olívia Salomé, Pereira Manuel Fernando Ribeiro, Parpot Píer, Oliveira César, Skiba Elżbieta, Jartych Elżbieta, Fonseca Antonio, Neves Isabel Correia |
| Dyscypliny: | |
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| Rok wydania: | 2020 |
| Wersja dokumentu: | Elektroniczna |
| Język: | angielski |
| Wolumen/Tom: | 1206 |
| Numer artykułu: | 127687 |
| Strony: | 1 - 10 |
| Impact Factor: | 3,196 |
| Web of Science® Times Cited: | 8 |
| Scopus® Cytowania: | 11 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | NIE |
| Abstrakty: | angielski |
| Two different methods A and B were used for preparing binuclear furanyl-azine metal complexes encapsulated in NaY zeolite. These new heterogeneous catalysts based on Fe(II) or Cu(II) complexes with a metal/ligand molar ratio of 2:1, were characterized by different spectroscopic techniques and chemical analysis which confirm the presence of the metal complexes inside the supercages of the zeolite. Mössbauer spectroscopy technique analysis confirms the presence of the Fe3+- complexes in octahedral coordination. The new heterogeneous catalysts were catalytic evaluated by phenol hydroxylation and compared with the encapsulated metal furanyl-azine complexes in NaY zeolite. The zeolite themselves do not present any activity and the presence of the metal complexes improve their activity. All heterogeneous catalysts enhance higher conversion of phenol to catechol. |
