Preparation, Thermal, and Mechanical Characterization of UV-Cured Polymer Biocomposites with Lignin
Artykuł w czasopiśmie
MNiSW
100
Lista 2021
| Status: | |
| Autorzy: | Goliszek Marta, Podkościelna Beata, Klepka Tomasz, Sevastyanova Olena |
| Dyscypliny: | |
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| Rok wydania: | 2020 |
| Wersja dokumentu: | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 5 |
| Wolumen/Tom: | 12 |
| Numer artykułu: | 1159 |
| Strony: | 1 - 18 |
| Impact Factor: | 4,329 |
| Web of Science® Times Cited: | 22 |
| Scopus® Cytowania: | 26 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | TAK |
| Licencja: | |
| Sposób udostępnienia: | Witryna wydawcy |
| Wersja tekstu: | Ostateczna wersja opublikowana |
| Czas opublikowania: | W momencie opublikowania |
| Data opublikowania w OA: | 19 maja 2020 |
| Abstrakty: | angielski |
| The preparation and the thermal and mechanical characteristics of lignin-containing polymer biocomposites were studied. Bisphenol A glycerolate (1 glycerol/phenol) diacrylate (BPA.GDA) was used as the main monomer, and butyl acrylate (BA), 2-ethylhexyl acrylate (EHA) or styrene (St) was used as the reactive diluent. Unmodified lignin (L) or lignin modified with methacryloyl chloride (L-M) was applied as an ecofriendly component. The influences of the lignin, its modification, and of the type of reactive diluent on the properties of the composites were investigated. In the biocomposites with unmodified lignin, the lignin mainly acted as a filler, and it seemed that interactions occurred between the hydroxyl groups of the lignin and the carbonyl groups of the acrylates. When methacrylated lignin was applied, it seemed to take part in the creation of a polymer network. When styrene was added as a reactive diluent, the biocomposites had a more homogeneous structure, and their thermal resistance was higher than those with acrylate monomers. The use of lignin and its methacrylic derivative as a component in polymer composites promotes sustainability in the plastics industry and can have a positive influence on environmental problems related to waste generation. |
