Synthesis and characterization of a novel composites derived from SBA-15 mesoporous silica and iron pentacarbonyl
Artykuł w czasopiśmie
MNiSW
100
Lista 2021
| Status: | |
| Autorzy: | Ruchomski Leszek, Pikula Tomasz, Kamiński Daniel, Słowik Grzegorz, Kosmulski Marek |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2022 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | Pt 3 |
| Wolumen/Tom: | 608 |
| Strony: | 2421 - 2429 |
| Web of Science® Times Cited: | 3 |
| Scopus® Cytowania: | 3 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | TAK |
| Licencja: | |
| Sposób udostępnienia: | Witryna wydawcy |
| Wersja tekstu: | Ostateczna wersja opublikowana |
| Czas opublikowania: | W momencie opublikowania |
| Data opublikowania w OA: | 30 października 2021 |
| Abstrakty: | angielski |
| Hypothesis Fe(CO)5 was deposited on SBA-15 from gaseous phase and the adsorbed iron precursor was oxidized and hydrolyzed. We hypothesize that a novel method produces composites of unique and useful properties. The absence of sulfur and halides in the composites is of special importance with respect of their potential application as catalysts and catalyst supports. Experiments We obtained composites containing 1.3–157.5% of iron oxide with respect to silica (counted as 100%). The new materials were characterized by specific surface area, XRD (X-ray diffraction), Mossbauer spectroscopy, electron microscopy coupled with EDS (energy dispersive X-Ray spectroscopy), and microelectrophoresis. Findings In the composites low in iron (<57% of iron oxide) the Mossbauer spectra showed only doublets, which were interpreted as tiny nanoparticles of Fe(III) oxide in the pores of SBA-15. In the composites high in iron (>65%) the Mossbauer spectra showed doublets and sextets. The later were interpreted as larger nanocrystals of hematite, and the presence of such nanocrystals was confirmed by XRD. EDS confirmed that in the composites low in iron, iron oxide was evenly distributed in the entire volume of pores of SBA-15. |
