Electric Double Layer in Water-Organic Mixed Solvents: Titania in 50% Ethylene Glycol
Artykuł w czasopiśmie
MNiSW
140
Lista 2021
| Status: | |
| Autorzy: | Kosmulski Marek, Mączka Edward |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2022 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 7 |
| Wolumen/Tom: | 27 |
| Numer artykułu: | 2162 |
| Strony: | 1 - 9 |
| Impact Factor: | 4,6 |
| Web of Science® Times Cited: | 5 |
| Scopus® Cytowania: | 5 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Finansowanie: | This research was supported by Lublin University of Technology, grant numbers MK FD-EE-407, EM FD-EE-413. |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | TAK |
| Licencja: | |
| Sposób udostępnienia: | Witryna wydawcy |
| Wersja tekstu: | Ostateczna wersja opublikowana |
| Czas opublikowania: | W momencie opublikowania |
| Data opublikowania w OA: | 27 marca 2022 |
| Abstrakty: | angielski |
| Ethylene glycol (EG) and its mixtures with water are popular components of nanofluids used as heat transfer fluids. The stability of nanofluids against coagulation is correlated with their zeta potential. The electrophoretic mobility of titania nanoparticles in 50-50 w/w EG was studied as a function of the concentration of various solutes. HCl, NaOH, SDS and CTMABr at concentrations up to 0.01 M are strong electrolytes in 50% EG, that is, the conductance of their solutions is proportional to the concentration. HCl, NaOH and CTMABr were very efficient in inducing a high zeta potential for titania in 50% EG. NaOH induced a negative zeta potential in excess of 70 mV, and HCl and CTMABr induced a positive zeta potential in excess of 70 mV at concentrations below 10−4 M. Apparently, HCl, NaOH and CTMABr are also more efficient than SDS in terms of nanofluid stabilization against coagulation. An overdose of base (>1 mM) results in depression of the negative zeta potential. This result may be due to the specific adsorption of sodium on titania from 50% EG. |
