Zeolite Composite Materials from Fly Ash: An Assessment of Physicochemical and Adsorption Properties
Artykuł w czasopiśmie
MNiSW
140
Lista 2023
Status: | |
Autorzy: | Mokrzycki Jakub, Franus Wojciech, Panek Rafał, Sobczyk Maciej, Rusiniak Piotr, Szerement Justyna, Jarosz Renata, Marcińska-Mazur Lidia, Bajda Tomasz, Mierzwa-Hersztek Monika |
Dyscypliny: | |
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Rok wydania: | 2023 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Numer czasopisma: | 6 |
Wolumen/Tom: | 16 |
Numer artykułu: | 2142 |
Strony: | 1 - 21 |
Impact Factor: | 3,1 |
Web of Science® Times Cited: | 11 |
Scopus® Cytowania: | 12 |
Bazy: | Web of Science | Scopus |
Efekt badań statutowych | NIE |
Finansowanie: | This study was funded within the TEAM-NET programme of the Foundation for Polish Science co-financed by the European Union under the European Regional Development Fund under project no. POIR.04.04.00-00-14E6/18, “Fly ash as the precursor of functionalized materials for applications in environmental engineering, civil engineering, and agriculture”. |
Materiał konferencyjny: | NIE |
Publikacja OA: | TAK |
Licencja: | |
Sposób udostępnienia: | Witryna wydawcy |
Wersja tekstu: | Ostateczna wersja opublikowana |
Czas opublikowania: | W momencie opublikowania |
Data opublikowania w OA: | 7 marca 2023 |
Abstrakty: | angielski |
Waste fly ash, with both low (with the addition of vermiculite) and high contents of unburned coal, were subjected to hydrothermal syntheses aiming to obtain zeolite composite materials—zeolite + vermiculite (NaX–Ver) and zeolite + unburned carbon (NaX–C). The composites were compared with parent zeolite obtained from waste fly ash with a low content of unburned carbon (NaX–FA). In this study, the physicochemical characteristics of the obtained materials were evaluated. The potential application of the investigated zeolites for the adsorption of ammonium ions from aqueous solutions was determined. Composite NaX–Ver and parent zeolite NaX–FA were characterized by comparable adsorption capacities toward ammonium ions of 38.46 and 40.00 mg (NH4+) g−1, respectively. The nearly 2-fold lower adsorption capacity of composite NaX–C (21.05 mg (NH4+) g−1) was probably a result of the lower availability of ion exchange sites within the material. Adsorbents were also regenerated using 1 M NaCl solution at a pH of 10 and subjected to 3 cycles of adsorption–desorption experiments, which proved only a small reduction in adsorption properties. This study follows the current trend of waste utilization (fly ash) and the removal of pollutants from aqueous solutions with respect to their reuse, which remains in line with the goals of the circular economy. |