Microstructural characterization and the influence of the chemical composition of the raw material mix on the physicochemical characteristics of waste-derived ceramic aggregates
Artykuł w czasopiśmie
MNiSW
140
Lista 2024
Status: | |
Autorzy: | Bandura Lidia, Pałka Krzysztof, Leśniak Magdalena, Franus Wojciech |
Dyscypliny: | |
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Rok wydania: | 2024 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Wolumen/Tom: | 84 |
Numer artykułu: | 108376 |
Strony: | 1 - 17 |
Impact Factor: | 6,7 |
Web of Science® Times Cited: | 3 |
Scopus® Cytowania: | 2 |
Bazy: | Web of Science | Scopus |
Efekt badań statutowych | NIE |
Finansowanie: | This research was funded by the National Center for Research and Development of Poland grant number POIR.04.01.04-00-0019/20. |
Materiał konferencyjny: | NIE |
Publikacja OA: | NIE |
Abstrakty: | angielski |
This work presents the possibility of using a mixture of different mining and industrial wastes (fly ash, waste rock, glass cullet and waste solution as a binder) for ceramic aggregate production with the application of microwave radiation. The effect of the chemical composition of the raw ma- terial mix reflected by F/SA ratio (flux oxides/SiO2 + Al2O3) on the mechanical and micro- structural properties of the aggregates was evaluated using X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM), and X-ray nanotomography (nCT). A higher proportion of fly ash relative to waste rock in the mixture composition led to an increase in the F/SA ratio. The greater the F/SA, the higher the values of particle density and compressive strength, ranging from 1.72 to 1.87 g/cm3 and 6.31–7.31 MPa, respectively. Moreover, higher F/ SA led to lower water absorption and porosity, which oscillated between 2.12 - 3.44% and 3.22–5.00%, respectively. X-ray nanotomography studies revealed an increasing contribution of larger pores with a radius of and an overall increase in porosity as the F/SA ratio rose. This finding was further confirmed by SEM investigations. TG-QMS analysis showed that organic matter could act as a pore-forming agent. The basic physical and mechanical paramaters of the obtained ceramic aggregates indicate the suitability of the studied wastes for the production of valuable construction materials. |