Macro- and microstructural evolution of cement paste modified with MWCNTs under thermal shock conditions
Artykuł w czasopiśmie
MNiSW
140
Lista 2024
Status: | |
Autorzy: | Szeląg Maciej, Rajczakowska Magdalena, Rumiński Patryk, Franus Wojciech, Cwirzen Andrzej |
Dyscypliny: | |
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Rok wydania: | 2024 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Wolumen/Tom: | 93 |
Numer artykułu: | 109919 |
Strony: | 1 - 19 |
Impact Factor: | 6,7 |
Web of Science® Times Cited: | 0 |
Scopus® Cytowania: | 0 |
Bazy: | Web of Science | Scopus | SCImago Journal Rank (SJR) SNIP |
Efekt badań statutowych | NIE |
Finansowanie: | This work was financially supported by the Polish National Agency for Academic Exchange under the Bekker programme, PPN/BEK/2020/1/00014/U/DRAFT/00001 |
Materiał konferencyjny: | NIE |
Publikacja OA: | TAK |
Licencja: | |
Sposób udostępnienia: | Witryna wydawcy |
Wersja tekstu: | Ostateczna wersja opublikowana |
Czas opublikowania: | W momencie opublikowania |
Data opublikowania w OA: | 13 czerwca 2024 |
Abstrakty: | angielski |
The study investigates the influence of multi-walled carbon nanotubes (MWCNTs) on the macro- and microstructure of cement paste (CP) subjected to thermal shock conditions. CPs with 0–0.3 % MWCNTs content, exposed to a sudden temperature load in a range 50–600 °C, were analyzed in terms of mechanical properties, chemical and phase composition, air pore structure, and microstructure of cement hydration products (Si/Ca, Al/Ca, portlandite, unhydrated part of cement). The research found the optimum MWCNT range to be 0.05–0.1 %, enhancing CP's thermal performance by strengthening cement hydration products and their cohesion, by more the nucleation effect than bridging effect. With the application of MWCNTs, the density of the solid cement phase increased, and the amount of the unhydrated part of cement decreased by up to 21.5 %, at 0.1 % MWCNTs content. Unfortunately, the increase in the MWCNTs content resulted in an increase in the pore volume in the worst case, up to 12.7 %, but it did not negatively affect the strength parameters. The MWCNTs effect caused an increase in tensile strength (fcf) by up to 41.0 % at temperatures above 400 °C, where in the most favorable case improvement in compressive strength reached 16.7 %. The study showed that MWCNTs as an admixture to cement composites is suitable for environments where there is a high variability in terms of thermal loads. |