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Microstructural, Electrical, and Tribomechanical Properties of Mo-W-C Nanocomposite Films
Artykuł w czasopiśmie
MNiSW
100
Lista 2024
Status: | |
Autorzy: | Smyrnova Kateryna V., Ivashchenko Volodymyr I., Sahul Martin, Čaplovič Ľubomír , Skrynskyi Petro , Kozak Andrii , Konarski Piotr, Kołtunowicz Tomasz, Gałaszkiewicz Piotr, Bondariev Vitalii, Żukowski Paweł, Budzyński Piotr, Borba-Pogrebnjak Svitlana O., Kamiński Mariusz, Bónová Lucia , Beresnev Vyacheslav M., Pogrebnjak Alexander D. |
Dyscypliny: | |
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Rok wydania: | 2024 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Numer czasopisma: | 12 |
Wolumen/Tom: | 14 |
Numer artykułu: | 1061 |
Strony: | 1 - 28 |
Impact Factor: | 4,4 |
Web of Science® Times Cited: | 0 |
Scopus® Cytowania: | 0 |
Bazy: | Web of Science | Scopus |
Efekt badań statutowych | NIE |
Finansowanie: | This study was funded by the Government Office of the Slovak Republic through the NextGenerationEU: Recovery and Resilience Plan for Slovakia (Grants No. 09I03-03-V01-00026, 09I03-03-V01-00027, and 09I03-03-V01-00067) and by the Slovak Research and Development Agency (Grany No. APVV-21-0231) and supported by the Ministry of Science and Higher Education (Poland) for the Lublin University of Technology for activities in Automation, Electronics, Electrical Engineering, and Space Technology (Grants No. FD-20/EE-2/701 and FD-20/EE-2/703) and for activities in Mechanical Engineering (Grants No. FD-20/IM-5/012 and FD-20/IM-5/051). |
Materiał konferencyjny: | NIE |
Publikacja OA: | TAK |
Licencja: | |
Sposób udostępnienia: | Witryna wydawcy |
Wersja tekstu: | Ostateczna wersja opublikowana |
Czas opublikowania: | W momencie opublikowania |
Data opublikowania w OA: | 20 czerwca 2024 |
Abstrakty: | angielski |
This study investigates the phase composition, microstructure, and their influence on the properties of Mo-W-C nanocomposite films deposited by dual-source magnetron sputtering. The synthesised films consist of metal carbide nanograins embedded in an amorphous carbon matrix. It has been found that nanograins are composed of the hexagonal β-(Mo2 + W2)C phase at a low carbon source power. An increase in the power results in the change in the structure of the carbide nanoparticles from a single-phase to a mixture of the β-(Mo2 + W2)C and NaCl-type α-(Mo + W)C(0.65≤k≤1) solid-solution phases. The analysis of electrical properties demonstrates that the nanograin structure of the films favours the occurrence of hopping conductivity. The double-phase structure leads to a twofold increase in the relaxation time compared to the single-phase one. Films with both types of nanograin structures exhibit tunnelling conductance without the need for thermal activation. The average distance between the potential wells produced by the carbide nanograins in nanocomposite films is approximately 3.4 ± 0.2 nm. A study of tribomechanical properties showed that Mo-W-C films composed of a mixture of the β-(Mo2 + W2)C and α-(Mo + W)C(0.65≤k≤1) phases have the highest hardness (19–22 GPa) and the lowest friction coefficient (0.15–0.24) and wear volume (0.00302–0.00381 mm2). Such a combination of electrical and tribomechanical properties demonstrates the suitability of Mo-W-C nanocomposite films for various micromechanical devices and power electronics. |