Metastable zone width of different solute-solvent systems during cooling crystallization: Experimental observations and their interpretation
Artykuł w czasopiśmie
MNiSW
100
Lista 2024
| Status: | |
| Autorzy: | Sangwal Keshra, Polak Wiesław |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2025 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 1 |
| Wolumen/Tom: | 71 |
| Strony: | 1 - 26 |
| Impact Factor: | 1,9 |
| Web of Science® Times Cited: | 3 |
| Scopus® Cytowania: | 3 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | NIE |
| Abstrakty: | angielski |
| Experimental observations of metastable zone width (MSZW) of various solute solvent systems obtained by cooling crystallization at controlled rates RL are reviewed and interpreted from the standpoint of deterministic theoretical models based on the classical three-dimensional (3D) nucleation theory containing two nucleation parameters: effective solid solvent interfacial energy γeff and preexponential factor A for nucleation. After a brief introduction to the parameters F and F1 of the models in terms of nucleation parameters of the classical nucleation theory and the effects of additives contained in the solution on the nucleation parameters A and γeff, typical experimental data of MSZW for selected solute solvent systems are described and discussed according to the models to observe general trends of variations of γeff and A as functions of solution saturation temperature T0 and concentration ci of additives contained in the saturated solutions of different systems. Thereafter the observed general trends of variations of γeff and A as functions of solution saturation temperature T0, solvent and concentration ci of additives contained in the saturated solutions of different systems are discussed. The di- mensions of 3D nuclei formed during MSZW of different systems and the limitations and applicability of deterministic models in crystalliza |
