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A bistable effect on a laminate structure with a piezoelectric patch was tested to harvest kinetic energy. The composite bistable plate was prepared in the autoclave with two different orientations of the glass fibers. The dynamic tests were performed on the universal testing machine using cyclic vertical compression excitation. During the tests, the bottom edge of the plate was clamped firmly while its upper edge was attached with some clearance to enable sliding. In such a configuration, the friction force between the plate and upper clamp element is responsible for the plate excitation. Simultaneously, the plate has enough space to change the shape between the two equilibria. During the harmonic excitation of the testing machine operating mode, a piezoelectric element was placed on the bistable plate and its voltage and normalized power outputs were evaluated. The experiments were repeated with additional mass distribution, which influenced the natural frequency of the plate.