Magnetic Fe,Co-Nanocarbon Frameworks Derived from Fe-Doped Zeolitic Imidazolate Framework-67 as Highly Active Catalysts for 5-Hydroxymethylfurfural Oxidation
Artykuł w czasopiśmie
MNiSW
140
Lista 2024
| Status: | |
| Autorzy: | Bordeiasu Mihai, Gościańska Joanna, Panek Rafał, Nicolaev Adela, Jurca Bogdan, Parvulescu Vasile I., Coman Simona M. |
| Dyscypliny: | |
| Aby zobaczyć szczegóły należy się zalogować. | |
| Rok wydania: | 2025 |
| Wersja dokumentu: | Drukowana | Elektroniczna |
| Język: | angielski |
| Numer czasopisma: | 17 |
| Wolumen/Tom: | 18 |
| Numer artykułu: | e202500678 |
| Strony: | 1 - 13 |
| Web of Science® Times Cited: | 0 |
| Scopus® Cytowania: | 0 |
| Bazy: | Web of Science | Scopus |
| Efekt badań statutowych | NIE |
| Finansowanie: | M.B. kindly acknowledges the Council of Doctoral Studies (C.S.U.D), University of Bucharest, Romania for supporting and funding partially this work. S.M.C. kindly acknowledges the Romanian Ministry Research and Digitalization for the financial support provided through the grant PNRR-III-C9-2022-I5-18, ResPonSE—Project No. 760010/2022. |
| Materiał konferencyjny: | NIE |
| Publikacja OA: | NIE |
| Abstrakty: | angielski |
| Zeolitic imidazolate frameworks (ZIFs) have recently emerged as promising precursors for the synthesis of heteroatom-doped nanocarbon materials. The chemical and structural features of these frameworks are influenced by the synthesis methodology, which directly affects their catalytic efficiency and stability. This study aims to investigate such frameworks by exploring a Co-ZIF structure doped with iron. Part of the FexCoy-ZIF (x = 0.05–0.15; y = 0.95–0.85) precursors is directly pyrolyzed to form FexCoy-NPC (NPC—nanoporous carbon), while another part is coated with a silica shell, followed by the pyrolysis of the FexCoy-ZIF@SiO2 intermediates to produce FexCoy-NCF (NCF—nanocarbon framework). To elucidate their chemical, structural, and catalytic properties, the synthesized materials are comprehensively characterized and finally investigate in the base-free oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). The optimal catalyst (Fe0.15Co0.85-NCF) demonstrates complete conversion of HMF (>99.9%) to FDCA with a pretty high selectivity (82.4%) after 6 h reaction at 80 °C. The correlation of the catalytic features with the efficiency of the catalysts provides insight into the catalytic characteristics responsible for the highest HMF conversion and selectivity to FDCA. The stability and recyclability of the catalysts are also examined. |
