Dielectric losses in the composite cellulose-mineral oil-water nanoparticles: theoretical assumptions
Artykuł w czasopiśmie
MNiSW
45
Lista A
Status: | |
Autorzy: | Żukowski Paweł, Kołtunowicz Tomasz, Kierczyński Konrad, Rogalski Przemysław, Subocz Jan, Szrot Marek, Gutten Miroslav, Šebok Milan, Korenčiak Daniel |
Rok wydania: | 2016 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Numer czasopisma: | 3 |
Wolumen/Tom: | 23 |
Strony: | 1609 - 1616 |
Impact Factor: | 3,417 |
Web of Science® Times Cited: | 40 |
Scopus® Cytowania: | 43 |
Bazy: | Web of Science | Scopus |
Efekt badań statutowych | NIE |
Materiał konferencyjny: | NIE |
Publikacja OA: | TAK |
Licencja: | |
Sposób udostępnienia: | Witryna wydawcy |
Wersja tekstu: | Ostateczna wersja opublikowana |
Czas opublikowania: | Przed opublikowaniem |
Abstrakty: | angielski |
The paper presents an analysis of test results by Frequency Domain Spectroscopy (FDS) of the loss tangent (tgd) in electrotechnical pressboard impregnated with insulating oil and containingnanoparticles of water depending on the frequency of alternating current, sample temperature and degreeof moisture. We found tg dreduction in areas of low and ultra-low frequency. It is associated with relax-ation due to the hopping conductivity (tunnelling) ofelectrons between moisture nanoparticles occurring in the cellulose impregnated with insulating oil. Infrequency areas close to the local minimum of tgd and higher, relaxation does not depend on the moisture content and is associated with other polar molecules which are part of the cellulose. We developed a new method converting experimental frequency depen-dence of the loss angle tangent, measured by the FDSmethod to the reference temperature of 293 K (20°C),using the exponential dependence of the relaxation time on the temperature, was developed. The activa-tion energy of the relaxation time was determinedbased on the loss angle tangent of moist electrotech-nical pressboard impregnated with insulating oil. Itwas found that the variation in moisture content in the composite cellulose–mineral oil–water nanoparticles do not cause changes in the activation energy of the relaxation time. The conversion of experimental frequency dependence of the loss angle tangentdetermined by the FDS method to the reference temperature of 293 K (20°C) eliminates the temper-ature dependence in the areas of ultra-low and low frequencies occurring in the runs made directly on the basis of the measurement results. After calculating the frequency dependence of the loss angle tangent to the reference temperature, all that remains is its depen-dence on the moisture content |