Adsorption of BTX from aqueous solutions byNa-P1 zeolite obtained from fly ash
Artykuł w czasopiśmie
MNiSW
30
Lista A
Status: | |
Autorzy: | Bandura Lidia, Kołodyńska Dorota, Franus Wojciech |
Dyscypliny: | |
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Rok wydania: | 2017 |
Wersja dokumentu: | Drukowana | Elektroniczna |
Język: | angielski |
Wolumen/Tom: | 109 |
Strony: | 214 - 223 |
Impact Factor: | 3,441 |
Web of Science® Times Cited: | 70 |
Scopus® Cytowania: | 79 |
Bazy: | Web of Science | Scopus |
Efekt badań statutowych | NIE |
Materiał konferencyjny: | NIE |
Publikacja OA: | NIE |
Abstrakty: | angielski |
The adsorption of BTX (benzene, toluene, o- and p-xylene) from aqueous solution by synthetic zeolite Na-P1 obtained from fly ash was examined. The adsorbent was characterized by scanning electron microscope (SEM-EDS) and X-ray diffraction (XRD). Surface area and pore volume distribution were determined using a nitrogen adsorption/desorption isotherm. BTX adsorption tests, including the influence of contact time, sorption isotherms and the influence of initial concentration, were performed in a batch multicomponent system. The sorption capacity followed the order xylenes > toluene > benzene, and the removal efficiency decreased with an increase in initial BTX concentration. The process kinetics was evaluated using pseudo-first-order, pseudo-second-order and intraparticle diffusion models. The adsorption equilibrium was reached within 24 h and followed pseudo-second-order kinetics. The Langmuir, Freundlich and Temkin models were used to evaluate the adsorption capacity of Na-P1. The Langmuir model was found to be the most suitable for all BTX sorption from a multicomponent system. The calculated maximum adsorption capacities of Na-P1 (qmax) for benzene, toluene, o- and p-xylene were 0.032, 0.050, 0.147 and 0.129 respectively. |